全文获取类型
收费全文 | 12431篇 |
免费 | 1351篇 |
国内免费 | 646篇 |
专业分类
电工技术 | 342篇 |
综合类 | 584篇 |
化学工业 | 2826篇 |
金属工艺 | 687篇 |
机械仪表 | 2181篇 |
建筑科学 | 409篇 |
矿业工程 | 213篇 |
能源动力 | 231篇 |
轻工业 | 901篇 |
水利工程 | 102篇 |
石油天然气 | 277篇 |
武器工业 | 111篇 |
无线电 | 1783篇 |
一般工业技术 | 1571篇 |
冶金工业 | 233篇 |
原子能技术 | 139篇 |
自动化技术 | 1838篇 |
出版年
2024年 | 40篇 |
2023年 | 176篇 |
2022年 | 322篇 |
2021年 | 400篇 |
2020年 | 427篇 |
2019年 | 432篇 |
2018年 | 377篇 |
2017年 | 488篇 |
2016年 | 538篇 |
2015年 | 574篇 |
2014年 | 691篇 |
2013年 | 779篇 |
2012年 | 812篇 |
2011年 | 881篇 |
2010年 | 563篇 |
2009年 | 637篇 |
2008年 | 627篇 |
2007年 | 603篇 |
2006年 | 631篇 |
2005年 | 564篇 |
2004年 | 515篇 |
2003年 | 485篇 |
2002年 | 409篇 |
2001年 | 320篇 |
2000年 | 272篇 |
1999年 | 282篇 |
1998年 | 254篇 |
1997年 | 217篇 |
1996年 | 174篇 |
1995年 | 144篇 |
1994年 | 137篇 |
1993年 | 124篇 |
1992年 | 86篇 |
1991年 | 90篇 |
1990年 | 65篇 |
1989年 | 30篇 |
1988年 | 55篇 |
1987年 | 21篇 |
1986年 | 34篇 |
1985年 | 38篇 |
1984年 | 28篇 |
1983年 | 28篇 |
1982年 | 26篇 |
1981年 | 13篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1973年 | 2篇 |
1959年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
The curing behavior of two kinds of commercial powdered resol phenolic resins was studied by differential scanning calorimetry. Liquid‐state 13C‐NMR spectroscopy was used to aid in understanding the curing behavior by detecting the structure of powdered resins. The reaction mechanism was interpreted with the dependency of activation energy on the degree of conversion. The results indicate that there are differences in the curing mechanism between core and face phenolic resins. The curing process of core resin was faster than that of face resin at the same reaction temperature. The water added in the curing system played an important role of plasticizer or diluent according to different curing stages and water content. In the initial curing stage, water mainly diluted the system and retarded the curing reactions. However, at the higher degrees of conversion, water played the role of plasticizer to decrease the effect of diffusion on the curing reactions to make the curing reactions more complete. The excess water added in the curing system played the role of diluent at almost all stages during the curing process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1371–1378, 2003 相似文献
72.
73.
A series of monomers were prepared by reacting (meth)acryloyl chloride with 2,4‐dihydroxybenzophenone, 2,4‐dihydroxybenzaldehyde, and 2,4‐dihydroxyacetophenone, respectively. The monomers were polymerized in dimethylformamide (DMF) at 70°C using benzoyl peroxide as an initiator. Polymer–metal complexes were obtained from DMF solutions of polymers with an aqueous solution of metal ions. The polymers and polymer–metal complexes were characterized by elemental analysis and spectral studies. The IR spectra of these complexes suggest that the metals are coordinated through the oxygen of the carbonyl group and the oxygen of the phenolic–OH group. The electronic spectra, electron paramagnetic resonance (EPR) spectra, and magnetic moments of polychelates showed an octahedral and square planar structure for Ni(II) and Cu(II) complexes, respectively. X‐ray diffraction studies revealed that polychelates are highly crystalline. The thermal and electrical properties, catalytic activity, and structure–property relationships are discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2083–2090, 2003 相似文献
74.
基于差分相关的星载AIS信号帧同步 总被引:1,自引:0,他引:1
在星载AIS接收机中,船舶信号在传输过程中产生的大范围时延和多普勒频移,给正确解码带来了困难。针对这一问题,基于AIS帧结构特点,提出一种差分相关帧同步算法。算法中将AIS帧结构中训练序列、开始标志和结束标志设计为间隔式特征序列作为同步码,通过差分相关函数来实现帧同步。仿真实验结果表明,该算法有较好的抗频偏特性,且在低信噪比下,性能要优于差分卷积法。 相似文献
75.
Layered Li[Li0.12NizMg0.32−zMn0.56]O2 oxide cathodes containing lithium atoms in the transition metal layers were synthesized and characterized using X-ray diffraction (XRD), galvanostatic cycling, and differential scanning calorimetry (DSC). The Li[Li0.12NizMg0.32−zMn0.56]O2 cathodes deliver a specific discharge capacity of about 190 mAh/g at room temperature and 236 mAh/g at 55 °C when cycled between 2.7 and 4.6 V versus Li/Li+. Excellent capacity retention and smooth potential profiles at room and elevated temperatures over extended cycles suggest that this material does not convert into a spinel structure. 相似文献
76.
Sari Heikkinen Leila Alvila Tuula T. Pakkanen Terhi Saari Pekka Pakarinen 《应用聚合物科学杂志》2006,100(2):937-945
Drying, water fractions, and water distribution were investigated for pine, birch, and reed pulps and pine–birch, pine–reed, and pine–birch–reed pulp mixtures. Gravimetrically determined drying times showed that the drying rates of the pulps decreased at two to four inflection points. Characterizations of the dried pulps by differential scanning calorimetry (DSC) showed a faster removal of free water than freezing and nonfreezing bound waters; all decreased simultaneously, however. DSC also revealed the critical water contents at which the free water and freezing bound water disappeared. The gravimetrically determined inflection points of the drying curves corresponded with the critical points determined by DSC. NMR line widths and images produced by 1H‐NMR imaging revealed the nature and regions of the pulp drying. The constant growth rate of the NMR line widths with decreasing water content appeared to change at two inflection points, which fell approximately in the same water content regions as the inflection points of the drying curves. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 937–945, 2006 相似文献
77.
Yun‐He Zhang Qin‐Hua Liu Ya‐Ming Niu Shu‐Ling Zhang Dong Wang Zhen‐Hua Jiang 《应用聚合物科学杂志》2005,97(4):1652-1658
A series of block copolymers composed of poly(ether ether ketone) (PEEK) and poly(ether ether ketone ketone) (PEEKK) components were prepared from their corresponding oligomers via a nucleophlilic aromatic substitution reaction. Various properties of the copolymers were investigated with differential scanning calorimetry (DSC) and a tensile testing machine. The results show that the copolymers exhibited no phase separation and that the relationship between the glass‐transition temperature (Tg) and the compositions of the copolymers approximately followed the formula Tg = Tg1X1 + Tg2X2, where Tg1 and Tg2 are the glass‐transition‐temperature values of PEEK and PEEKK, respectively, and X1 and X2 are the corresponding molar fractions of the PEEK and PEEKK segments in the copolymers, respectively. These copolymers showed good tensile properties. The crystallization kinetics of the copolymers were studied. The Avrami equation was used to describe the isothermal crystallization process. The nonisothermal crystallization was described by modified Avrami analysis by Jeziorny and by a combination of the Avrami and Ozawa equations. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1652–1658, 2005 相似文献
78.
79.
Alexander A Minakov 《Polymer》2004,45(11):3755-3763
For poly(ethylene terephthalate) (PET) and other polymers the origin of the multiple melting peaks observed in differential scanning calorimetry (DSC) curves is still controversially discussed. This is due to the difficulty to investigate the melting of the originally formed crystals exclusively. Recrystallization is a fast process and most experimental techniques applied so far do not allow fast heating in order to prevent recrystallization totally. Developments in thin-film (chip) calorimetry allow scanning rates as high as several thousand Kelvin per second. We utilized a chip calorimeter based on a commercially available vacuum gauge, which is operated under non-adiabatic conditions. The calorimeter was used to study the melting of isothermally crystallized PET. Our results on melting at rates as high as 2700 K/s give clear evidence for the validity of a melting-recrystallization-remelting process for PET at low scanning rates (DSC). At isothermal conditions PET forms crystals, which all melt within a few dozens of K slightly above the isothermal crystallization temperature. There is no evidence for the formation of different populations of crystals with significantly different stability (melting temperatures) under isothermal conditions. Superheating of the crystals is of the order of 10 K at 2700 K/s. 相似文献
80.
The nonisothermal and isothermal crystallizations of low‐density polyethylene (LDPE) and polypropylene (PP) in phosphate glass (Pglass)–polymer hybrid blends were studied through differential scanning calorimetry (DSC). As the Pglass volume fraction was increased, the percentage crystallinity decreased. The half‐time for crystallization decreased as the propagation rate constant rose, for both of the polymer matrices, with increasing Pglass concentrations. The Pglass was observed to be a nucleating agent for formation of two‐ or three‐dimensional spherulites in the hybrids. Tensile modulus improved for both of the Pglass–polymer hybrids up to 40% Pglass, but the energy to break decreased. Tensile strength changed slightly with the addition of Pglass to the LDPE matrix, exhibiting a larger value than that of pure LDPE at 30%. The tensile strength decreased as more Pglass was added to the PP matrix. The observed differences between tensile properties of the Pglass–PP and Pglass–LDPE hybrids at identical Pglass volume concentration were found to be consistent with that of the crystallization behavior of the hybrids. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3445–3456, 2003 相似文献